101年 - 101 國立嘉義大學_碩士班(甲組)招生考試試題_應用化學系：無機化學#146268

科目：研究所、轉學考(插大)◆無機化學 | 年份：101年 | 選擇題數：0 | 申論題數：14

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所屬科目：研究所、轉學考(插大)◆無機化學

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申論題 (14)

(a) 4f electrons in Ce (Z=58)

(b) 3d electrons in Ni (Z=28).

(a) volume (m3) of the unit cell

(b)length parameter of the unit cell?

(c) the inter-ionic distance (r + + r - ) ?

(3) In the case of Cu (II) (d 9) , and Cr (II) (d 4 low spin),please employ the Jane-Teller effect to predict thepossible distortion that could be found in these twocompounds? (5%)

(a) Fe 2+

(b) Cu. (5%)

(a) CH3-CH3 + H2O → CH3OH + CH4 (△H = 12kcal/mol)

(b) CH3COCH3 + H2O → CH3COOH + CH4 (△H = -13kcal/mol )

(a) H2O, NH3 and PH3

(b) OH- , NH3, and NO2-

(c) calculate the η value for the hardest one among the 5compounds ?

(7) The point group of trans-1,2-dichloroethylene isC2h ,and has the reducible representation: