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104年 - 104 台灣聯合大學系統_學士班轉學生考試試題_A7:普通化學#139165
> 試題詳解
13. What is the central metal of chlorophyll (葉綠素)?
(A)Mg
(B)Cu
(C)Co
(D)Ni
(E)Co
答案:
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統計:
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14. What kind of information will be provided by the UV/VIS absorption spectroscopy? (A)Molecule rotation (B)Nuclear spin (C)Nuclear vibration (D)Electronic transition (E)Electron spin
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15. Esters undergo hydrolysis reactions with aqueous sodium hydroxide to give alcohols and acids. This well-known process is also called: (A)Hydrogenation (B)Oxidation (C)Saponification (D)Halogenation (E)Epoxidation
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16. Which of the following is incorrectly named? (A)SO4²⁻, sulfate ion (B)Cr2O7²⁻, dichromate ion (C)PO4³⁻, phosphate ion (D)ClO⁻, chlorite ion (E)CN⁻, cyanide ion
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17. A fuel-air mixture is placed in a cylinder fitted with a piston. The original volume is 0.320-L. When the mixture is ignited, gases are produced and 805 J of energy is released. To what volume will the gases expand against a constant pressure of 635 mmHg, if all the energy released is converted to work to push the piston? (A)9.19 L (B)6.96 L (C)9.83 L (D)9.51 L (E)1.59 L
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18. Which statement is true of a process in which one mole of a gas is expanded from state A to state B? (A)When the gas expands from state A to state B, the surroundings are doing work on the system. (B)The amount of work done in the process must be the same, regardless of the path. (C)It is not possible to have more than one path for a change of state. (D)The final volume of the gas will depend on the path taken. (E)The amount of heat released in the process will depend on the path taken.
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19. A sample of N2 gas is contaminated with a gas A of unknown molar mass. The partial pressure of each gas is known to be 200. torr at 25°C. The gases are allowed to effuse through a pinhole, and it is found that gas A escapes at 2 times the rate of N2. The molar mass of gas A is: (A)7.00 g/mol (B)56 g/mol (C)14.01 g/mol (D)112 g/mol (E)none of these
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20. Which of the following effects will make PV/nRT less than one for a real gas? (A)The gas molecules are large enough to occupy a substantial amount of space. (B)A large number of molecules have speeds greater than the average speed. (C)The gas molecules have a very low molar mass. (D)The gas molecules attract one another. (E)None of these.
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21. A solution contains the ions Ag+, Pb2+, and Ni2+. Dilute solutions of NaCl, Na2SO4, and Na2S are available to separate the positive ions from each other. In order to effect separation, the solutions should be added in which order? (A)Na2SO4, NaCl, Na2S (B)Na2SO4, Na2S, NaCl (C)Na2S, NaCl, Na2SO4 (D)NaCl, Na2S, Na2SO4 (E)NaCl, Na2SO4, Na2S
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22. Consider the reaction 3A + B + C → D + E where the rate law is defined as An experiment is carried out where [B]0 = [C]0 = 1.00 M and [A]0 = 1.00 × 10⁻⁴ M, and [A] = 3.26 × 10⁻⁵ M after 3.00 minutes. What is the half-life for this experiment? (A)111 s (B)87 s (C)60 s (D)17 s (E)none of these
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23. At 500.0 K, one mole of gaseous ONCl is placed in a one-liter container. At equilibrium it is 5.5% dissociated according to the equation shown here: 2ONCl ⇌ 2NO + Cl2. Determine the equilibrium constant. (A)9.3 × 10⁻⁵ (B)1.7 × 10⁻³ (C)5.8 × 10⁻² (D)9.5 × 10⁻¹ (E)1.1 × 10⁴
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